The University of Missouri at Columbia
Chemistry 2050 - Introduction to Organic Chemistry - Fall Semester 2005

Schedule
Last Update 12/05/05

Professor Dr. Rainer Glaser
Office 321 Chemistry Building
Telephone 882-0331
E-Mail GlaserR@missouri.edu
Course Site on WWW http://www.missouri.edu/~chemrg/RG_T_FS05.html

Nr. Day Date Topic Notes
1 M 8/22 Introduction Explore 2050f05 Web Site
2 T 8/23 1: Atoms & Lewis Structures Handouts for Exp. #1
3 W 8/24 1: Polar Bonds & Shapes of Molecules Work Problems 1.17 - 1.32 & 1.35
4 F 8/26 Lab. Lect. #1: Melting Points -
5 M 8/29 2: Alkanes, Isomers & Nomenclature O, O=O vs. .O-O., & Ozone
6 T 8/30 2: Conformation, Combustion, 1o, 2o & 3o Work Problems 2.23 - 2.28 & 2.32 - 2.42
7 W 8/31 2: Cycloalkanes, Names & Conformation Handouts for Exp. #2
8 F 9/2 Lab. Lect. #2: Recrystallization -
- M 9/5 LABOR DAY -
9 T 9/6 3: Intermolecular & Hydrogen Bonding Work Problems 3.16 - 17 & 3.26 - 3.28
10 W 9/7 3: Oil & Water, Acids & Bases Handouts for Expt. #3
11 F 9/9 3: Protonation & Carbenium Ions
Lab. Lect. #3: Distillation
Work Problems 3.29 - 3.33
12 M 9/12 4: Alkene & Alkynes: NSB & E/Z-Isomers -
13 T 9/13 4: Alkene & Alkynes: Preparation. -
14 W 9/14 TEST #1, Chapters 1 - 3 -
15 F 9/16 4: Elimination Regiochemistry
Lab. Lect. #4: Extraction
Handouts for Exp. #4
16 M 9/19 5: Hydrogenation & HX Additions (Br, Cl, OH) Work problems 4.18 - 4.20, 4.22 - 4.30, 4.36 - 4.38, 4.41
17 T 9/20 5: X-X Additions (Br, Cl) -
18 W 9/21 5: Acetylene Acidity et al. Handouts for Exp. #5
19 F 9/23 Lab. Lect. #5: TLC & Chromatography Work problems 5.16-5.18, 5.22, 5.23, 5.25-5.29
20 M 9/26 6: As, HAs & PAHs, o, m & p, benzyl cation -
21 T 9/27 6: Electrophilic Aromatic Substitution -
22 W 9/28 6: Substituent Effects Handouts for Exp. #6
23 F 9/30 Lab. Lect. #6: Nitration Work problems 6.16, 6.17, 6.19, 6.20, 6.22, 6.24-6.35.
24 M 10/3 7: Optical Activity, R/S -
25 T 10/4 7: Symmetry Elements, being meso -
26 W 10/5 7: Stereochemistry: Resolution Handouts for Exp. #7
27 F 10/7 Lab. Lect. #7: Nucl. Subst. Rates Work problems 7.15, 7.16, 7.18, 7.20-7.22, 7.24, 7.25, 7.29, 7.31 & 7.32.
28 M 10/10 8.1: Nucleophiles & Products
8.2-4: SN2 Kinetics, Sterics & Inversion
-
29 T 10/11 8.5-7: SN1 Kinetics, Sterics & Racemization -
30 W 10/12 TEST #2, Chapters 4 - 7 Handouts for Exp. #8
31 F 10/14 Lab. Lect. #8: Ester ID & Aspirin Synthesis Work problems 8.9, 8.11-17, 8.20 & 8.21.
32 M 10/17 9.1-4: BDEs and Methane Halogenations National Chemistry Week
33 T 10/18 9.5: Selectivity in Alkane Halogenations -
34 W 10/19 9.7-8: Additions & Polymerizations Handouts for Exp. #9
35 F 10/21 Lab. Lect. #9: ID Phenol/Alcohol/Ether Work problems 9.11-15 & 9.18-21
36 M 10/24 10.1-5: As from Cs, Cs from As -
37 T 10/25 10.8-12: Ethers & Epoxides -
38 W 10/26 10.13-17: Phenols & Phenol Ethers Handouts for Exp. #10
39 F 10/28 Lab. Lect. #10: ID of Aldehyde/Ketone Work problems 10.13-20, 10.24-27 & 10.30-31.
40 M 10/31 11.1-6: Carbonyls and Hydration -
41 T 11/1 11.7-9: Reactions with Alcohols & Amines -
42 W 11/2 10.10-13: Grignard Chemistry Handouts for Exp. #11
43 F 11/4 10.14-18: Enols, Enolates & Aldols
Lab. Lect. #11: Dyes & Dying
Work problems 11.17a&b, look over 11.19-21, work 11.22-24, 11.26-32, 11.33-35.
44 M 11/7 12.1-7: Acids, Salts & Soaps -
45 T 11/8 12.8-11: Preps. & Rxns. -
46 W 11/9 TEST #3, Chapters 8 - 11 Handouts for Exp. #12
47 F 11/11 Lab. Lect. #12: Nylon Work problems 12.9-20.
48 M 11/14 19.1-5: NMR & MRI Basics Handout EtOH-Spectra (1H- & 13C-NMR, IR, MS)
49 T 11/15 19.6-9: NMR Spectra & Structure Dr. Glaser Res. Lect., 12 pm, 103 Schlundt
50 W 11/16 19.10-11: UV/Vis- & IR-Spectroscopy -
51 F 11/18 19.13: Mass Spectrometry (MS, GC/MS, MS/MS) Work Problems 19.16-22, 19.26&27 and 19.30
- M 11/21 THANKSGIVING Read Chapter 13, mostly review.
- T 11/22 THANKSGIVING -
- W 11/23 THANKSGIVING -
- F 11/25 THANKSGIVING -
52 M 11/28 Review & Preparation for Lab Final -
53 T 11/29 Complete chapter 19 Teaching Evaluations
54 W 11/30 LAB FINAL -
55 F 12/2 14.1-6: Props. & Preps. of Amines Work problems 14.15, 14.17 and 14.19-30.
56 M 12/5 14.7-11: Nitrosation Chemistry
15.1-4: Carbohydrates I
-
57 T 12/6 15.5-9: Carbohydrates II -
58 W 12/7 18: DNA & Double Helix Focus Areas for Final Posted on BB
59 F 12/9 17: Amino Acids & Peptides -
- M 12/12 No Lecture -
- T 12/13 No Lecture -
- W 12/14 No Lecture -
- R 12/15 FINAL 10:30am-12:30pm -
- F 12/16 No Lecture -


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