Enantioselective Catalytic Acylation...

Authors

Departments of Chemistry, University of Missouri-Columbia, Columbia, Missouri 65211, Washington University, St. Louis, Missouri ...


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Figure _. Precoordination first row are RR
(R,R)
C2H---O(alc)
C3H---O(alc)
H/Ph
Ph(alc) far above arene
(R,R)
C2H---O(alc)
C3H---O(alc)
H/Et
Et(alc) far above arene
(R,R)
C2H---O(alc)
C3H---Ph(alc)
H/Et
Restart #3
(R,R)
C2H---O(alc)
C3H---Ph(alc)
H/Et
arene---Ph(alc)
(R,S)
C2H---O(alc)
C3H---O(alc)
H/Ph
Ph(alc) far above arene
(R,S)
C2H---O(alc)
C3H---O(alc)
H/Et
Et(alc) far above arene
(R,S)
C2H---O(alc)
C3H---Ph(alc)
H/Et
Running
(R,S)
C2H---O(alc)
C3H---Ph(alc)
H/Et
arene---Ph(alc)
(R,S)
C2H---O(alc)
C3H---Ph(alc)
Et/Ph




Figure _. CN-Additions
ecl stag
ecl-en stag-en


Figure _. CO-Additions
ecl stag
ecl-en stag-en