Enantioselective Catalytic Acylation...
Authors
Departments of Chemistry, University of Missouri-Columbia, Columbia, Missouri 65211, Washington University, St. Louis, Missouri ...
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Figure _. Precoordination first row are RR
| (R,R)
C2H---O(alc) C3H---O(alc) H/Ph Ph(alc) far above arene |
(R,R)
C2H---O(alc) C3H---O(alc) H/Et Et(alc) far above arene |
(R,R)
C2H---O(alc) C3H---Ph(alc) H/Et Restart #3 |
(R,R)
C2H---O(alc) C3H---Ph(alc) H/Et arene---Ph(alc) |
||
| (R,S)
C2H---O(alc) C3H---O(alc) H/Ph Ph(alc) far above arene |
(R,S)
C2H---O(alc) C3H---O(alc) H/Et Et(alc) far above arene |
(R,S)
C2H---O(alc) C3H---Ph(alc) H/Et Running |
(R,S)
C2H---O(alc) C3H---Ph(alc) H/Et arene---Ph(alc) |
||
| (R,S)
C2H---O(alc) C3H---Ph(alc) Et/Ph |
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Figure _. CN-Additions
| ecl | stag | ||
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| ecl-en | stag-en | ||
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Figure _. CO-Additions
| ecl | stag | ||
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| ecl-en | stag-en | ||
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